Bernd Goldfuss

Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions (2007)

Lange, Dominik A, Goldfuss, Bernd

Abstract Electronic differentiations in Pd-catalyzed allylic substitutions are assessed computationally from transition structure models with electronically modified phospha-benzene-pyridine ligands....

A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts (2006)

Goldfuss, Bernd, Löschmann, Thomas, Kop-Weiershausen, Tina, Neudörfl, Jörg, Rominger, Frank

Abstract The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.

A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts

Goldfuss, Bernd, Löschmann, Thomas, Kop-Weiershausen, Tina, Neudörfl, Jörg, Rominger, Frank

The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.

A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts

Goldfuss, Bernd, Löschmann, Thomas, Kop-Weiershausen, Tina, Neudörfl, Jörg, Rominger, Frank

The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.

Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions

Lange, Dominik A, Goldfuss, Bernd

Electronic differentiations in Pd-catalyzed allylic substitutions are assessed computationally from transition structure models with electronically modified phospha-benzene-pyridine ligands. Although...